✦ LIBER ✦

Reinvestigation of a criticized mechanistic probe study of metal hydride reductions of alkyl halides

✍ Scribed by Newcomb, Martin; Varick, Thomas R.; Choi, Seung Yong

Book ID: 127077480
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 832 KB
Volume: 57
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00027a065

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Relative reactivities of anionic transit

Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides

✍ Kao, S. C.; Darensbourg, Marcetta Y. 📂 Article 📅 1984 🏛 American Chemical Society 🌐 English ⚖ 294 KB

A quantitative analysis of “mechanistic

A quantitative analysis of “mechanistic probe” studies of reduction of alkyl iodides by lithium aluminum hydride supports a polar SN2 mechanism

✍ Martin Newcomb; Jere Kaplan; Dennis P. Curran 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 326 KB

Fast halogen abstractions from alkyl hal

Fast halogen abstractions from alkyl halides by alkyl radicals. Quantitation of the processes occurring in and a caveat for studies employing alkyl halide mechanistic probes

✍ Newcomb, Martin; Sanchez, Robert M.; Kaplan, Jere 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 705 KB

Spectroscopic evidence for the reduction

Spectroscopic evidence for the reduction of alkyl halides by metal hydrides via a single electron transfer mechanism

✍ E.C. Ashby; A.B. Goel; R.N. Depriest 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 207 KB

Alkyl Bromides as Mechanistic Probes of

Alkyl Bromides as Mechanistic Probes of Reductive Dehalogenation: Reactions of Vicinal Dibromide Stereoisomers with Zerovalent Metals

✍ Totten, Lisa A.; Jans, Urs; Roberts, A. Lynn 📂 Article 📅 2001 🏛 American Chemical Society 🌐 English ⚖ 105 KB

Evaluation of tributylgermanium hydride

Evaluation of tributylgermanium hydride as a reagent for the reductive alkylation of active olefins with alkyl halides

✍ Philip Pike; Susan Hershberger; James Hershberger 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 545 KB

The reductive alkylation of acrylonitrile and of 2-cyclohexen-l-one by alkyl halides using tributylgermanium hydride was systematically evaluated. The performance of the germanium reagent was