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Regularities and specific features of the reaction of oligohydroxyarylenes with aromatic diazo-compounds

โœ Scribed by B.I. Liogon'kii; R.Z. Aleksanyan; N.R. Avanesova; I.I. Tugov


Book ID
116047219
Publisher
Elsevier Science
Year
1984
Weight
471 KB
Volume
26
Category
Article
ISSN
0032-3950

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Pyrolysis of the relatively stable, solid complexes of cyclomaltoheptaose (/3cyclodextrin) with phenyldiazomethane, 1-diazo-1-phenylethane, and diazo-(diphenyl)methane results in degradation of the labile guests. The host matrix exerts "reaction-vessel" and "shape-selectivity" effects upon the reac