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Regioselectivity of the insertion reactions of some aromatic diazo compound complexes with cyclomaltoheptaose

โœ Scribed by Shelley H. Smith; Sarah M. Forrest; David C. Williams Jr.; Margaret F. Cabell; Michael F. Acquavella; Christopher J. Abelt


Book ID
107727152
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
662 KB
Volume
230
Category
Article
ISSN
0008-6215

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๐Ÿ“œ SIMILAR VOLUMES


Complexes of cyclomaltoheptaose with aro
โœ Christopher J. Abelt; Jonathan S. Lokey; Shelley H. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 880 KB

Pyrolysis of the relatively stable, solid complexes of cyclomaltoheptaose (/3cyclodextrin) with phenyldiazomethane, 1-diazo-1-phenylethane, and diazo-(diphenyl)methane results in degradation of the labile guests. The host matrix exerts "reaction-vessel" and "shape-selectivity" effects upon the reac