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Insertion reactions of diazo compounds with some selenium(II) electrophiles

✍ Scribed by Thomas G. Back; Russell G. Kerr


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
803 KB
Volume
286
Category
Article
ISSN
0022-328X

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## Abstract **A happy ending**: The germanium(II) hydride [LGeH], where L=[HC{(CMe)(2,6‐__i__Pr~2~C~6~H~3~N)}~2~], reacts with a diazoalkane to form the hydrazone derivative (see picture). The reaction proceeds through the unprecedented end‐on nitrogen insertion of the diazo compound.magnified imag