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Regiospecific total synthesis of 6-deoxyanthracyclines: 4-demethoxy-6-deoxydaunorubicin

โœ Scribed by Penco, Sergio; Angelucci, Francesco; Arcamone, Federico; Ballabio, Marzia; Barchielli, Giovanna; Franceschi, Giovanni; Suarato, Antonino; Vanotti, Ermes

Book ID
127100420
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
260 KB
Volume
48
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Asymmetric Synthesi
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## Asymmetric Synthesis and DNA Intercalation of (-)-6-(((Aminoalkyl)oxy) methyl)-4-demethoxy-6,7dideoxydaunomycinones. -Asymmetric BF3โ€ขEt2O promoted Diels-Alder addition of (I) with ( II) gives the best diastereoselectivity to lead to one major monoadduct. This is added to in situ generated dide