Regiospecific carboncarbon bond formation by oxidative coupling of η1-allyl or η1-propargyl ligands of organoiron complexes
✍ Scribed by Paul S. Waterman; Warren P. Giering
- Book ID
- 108354245
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 295 KB
- Volume
- 155
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
The reaction of [meso-(ebthi)TiCl 2 ] [ebthi = 1,2-ethylene-6a. In the analogous reactions of the complexes [(thi) 2 Ti(η 2 -PhC 2 SiMe 3 )] (thi = η 5 -tetrahydroindenyl), [rac-(ebthi)Ti(η 2 -1,1Ј-bis(η 5 -tetrahydroindenyl)] with magnesium in the presence of the alkynes Me 3 SiCϵCSiMe 3 and PhCϵCS
## Abstract Reactions of the chiral racemic carbonyl complex [(η^5^‐C~5~Me~5~)Re(NO)(NCCH~3~)(CO)]^+^·BF~4~^−^ and diphosphanes Ph~2~P(CH~2~)~__n__~PPh~2~ [2.4:1.0 mol ratio; __n__ = 10 (a), 14 (b)] give the (bridging phosphane)dirhenium complexes [(η^5^‐C~5~Me~5~)Re(NO)(CO){μ‐[PPh~2~(CH~2~)~__n__~