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The Effect of Chloride Ions on the Mechanism of the Oxidative Addition of Cyclic Allylic Carbonates to Pd0 Complexes by Formation of Neutral[(η1-allyl)PdClL2] Complexes

✍ Scribed by Thibault Cantat; Nicolas Agenet; Anny Jutand; Roser Pleixats; Marcial Moreno-Mañas


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
214 KB
Volume
2005
Category
Article
ISSN
1434-193X

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The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h