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Regiospecific alkyne-formate ester reactions catalyzed by palladium(0)

โœ Scribed by Howard Alper; Manuel Saldana-Maldonado; van J.B. Lin


Publisher
Elsevier Science
Year
1988
Weight
208 KB
Volume
49
Category
Article
ISSN
0304-5102

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Regiospecifically controlled formation o
โœ F. Guibรฉz; Yang Ting Xian; A.M. Zigna; G. Balavoine ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 275 KB

The paZZadium-catalyzed hydrostannolysis of a-disubstituted ally1 B-keto esters yields the corresponding tributyltin B-keto carboxylates which loose carbon dioxide at very moderate temperature, thus leading to the regiospeeifie formation of tributyltin tetrambstituted enolates.