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Palladium-catalyzed formate-nitrobenzene-carbon monoxide reaction: Formation of carbamate ester

✍ Scribed by Ivan J.B. Lin; Ching-Sheng Chang


Publisher
Elsevier Science
Year
1992
Weight
338 KB
Volume
73
Category
Article
ISSN
0304-5102

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Palladium-Catalyzed Hydroesterification
✍ Yuko Katafuchi; Tetsuaki Fujihara; Tomohiro Iwai; Jun Terao; Yasushi Tsuji 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 258 KB

## Abstract A highly efficient hydroesterification of alkynes employing aryl formates has been developed without the use of external carbon monoxide and at ambient pressure. The reaction in the presence of a palladium‐xantphos catalyst system selectively affords α,β‐unsaturated esters in good to hi