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Regiospecific addition of methoxycyclohexa-1,3-dienes to 2-methoxy-1,4-benzoquinone. Application to the synthesis of 3-methoxy-7-methyljuglone and α-caryopterone.

✍ Scribed by Robin G.F. Giles; Gregory H.P. Roos


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
106 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis


Nucleophilic attack on 1,4-benzoquinone leads in general to 2,5-disubstituted 1,4benzoquinones'.

For example, the action of methanol on benzoquinone, in the presence of zinc n


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