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ChemInform Abstract: Chiral Benzoquinones as a New Class of Ligands for Asymmetric Catalysis: Synthesis and Application to the Palladium(II)-Catalyzed 1,4-Dialkoxylation of 1,3-Dienes.

✍ Scribed by K. ITAMI; A. PALMGREN; A. THORARENSEN; J.-E. BAECKVALL


Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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ChemInform Abstract: Palladium(II)-Catal
✍ Andreas Palmgren; Anna L. E. Larsson; Jan-E. Baeckvall; Paul Helquist πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB

Palladium(II)-Catalyzed 1,4-Oxidation of 2-Aryl-1,3-cyclohexadienes. Application to the Synthesis of (Β±)-Epibatidine and Analogues. -1,4-Chloroacetoxylation of arenes (I) in the presence of palladium(II) catalyst gives cis-cyclohexenes (III) with high regio-and stereoselectivity. These products are