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Regioselectivity of Oxysulfenylations of Cycloocta-1,5-diene

✍ Scribed by Klaus Hegemann; Birgit Wibbeling; Prof. Dr. Günter Haufe

Book ID
105354931
Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
415 KB
Volume
340
Category
Article
ISSN
1615-4150

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Tsuji and Takahashi(1) reported that the complex I undergoes various transformations at the cyclooctenyl ligand on treatment with borohydride, alkoxide, and alkali to give 2-(cyclooctyl)malonate(II), 2-(cyclooct-5-enyl)-malonate(III), and 2-(cycloocta-3,5-dienyl)-malonate(IV) respectively.