๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Transformation of cycloocta-1,5-diene through its palladium complex

โœ Scribed by Masaru Tada; Yasuto Kuroda; Tadashi Sato

Book ID
104239621
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
175 KB
Volume
10
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Tsuji and Takahashi(1) reported that the complex I undergoes various transformations at the cyclooctenyl ligand on treatment with borohydride, alkoxide, and alkali to give 2-(cyclooctyl)malonate(II), 2-(cyclooct-5-enyl)-malonate(III), and 2-(cycloocta-3,5-dienyl)-malonate(IV) respectively.

๐Ÿ“œ SIMILAR VOLUMES

The Dynamic Behaviour and NMR Solution s
The Dynamic Behaviour and NMR Solution structures of complexes of the type (Bisphosphine)(cycloocta-1,5-diene)iridium(I) and the X-ray crystal structure of (cycloocta-1,5-diene)((โˆ’)-norphos)iridium(I) hexafluorophosphate
โœ Werner J. Hรคlg; Lars R. ร–hrstrรถm; Heinz Rรผegger; Luigi M. Venanzi; Tobias Gerfin ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 944 KB

## Abstract A squareโ€planar coordination geometry was found for the complex [Ir(cod){(โˆ’)โ€norphos}][PF~6~] (1b[PF~6~]; cod = cylcooctaโ€1,5โ€diene and (โˆ’)โ€norphos = [(2__R__,3__R__)โ€8โ€9โ€10โ€trinorbornโ€5โ€eneโ€2,3โ€diyl]bis(diphenylphosphine)) in the solid state by Xโ€ray diffraction. Crystal data: monoclin