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Regioselectivity of addition of thiols and amines to conjugated allenic ketones and esters

✍ Scribed by Sugita, Toshio; Eida, Mitsuru; Ito, Hiroshi; Komatsu, Naoki; Abe, Kazuaki; Suama, Masakazu


Book ID
127196044
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
717 KB
Volume
52
Category
Article
ISSN
0022-3263

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Regioselective Michael addition of thiol
✍ Akio Kamimura; Norikazu Murakami; Kakuteru Yokota; Masashi Shirai; Hiroaki Okamo πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 145 KB

The regiochemistry of the Michael addition of thiols to tertiary fumaric amide esters was efficiently controlled in the presence or absence of base; either of the two isomers was prepared in a highly selective way.