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Regioselectivity in intramolecular addition of allylsilanes to conjugated dienones

โœ Scribed by George Majetich; Ken Hull; Jean Defauw; Richard Desmond

Book ID
108382582
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
227 KB
Volume
26
Category
Article
ISSN
0040-4039

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The site of Michaeladditionof ~-heteroatom substitutedthiols (such as mercaptoethanol)to unsubstituted2, 4-diectoneand 2, 4, 6-trienonesis at the terminal(en)position. This site preferenceis transferred to the (3site when the addition is accomplishedusing Ti+4 complexation. These ~site additionprodu