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Allylsilanes as Carbon Nucleophiles in Intramolecular Pd(II)-Catalyzed 1,4-Addition to Conjugated Dienes

✍ Scribed by Castano, Ana M.; Baeckvall, Jan-E.


Book ID
127111434
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
279 KB
Volume
117
Category
Article
ISSN
0002-7863

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The use of stabilized carbon nucleophile
✍ Magnus RΓΆnn; Pher G. Andersson; Jan-E. BΓ€ckvall πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 199 KB

Palladium(lI)-catalyzed aerobic oxidation of conjugated dienes 3 having a stabilized carbon nucleophile in the side chain resulted in a carbecyclization with an overall 1,4-cis-addition to the diene. The reactions were carried under an atmosphere of molecular oxygen in DMSO. An interesting exolendo