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Regioselectivity associated with the 1,3-dipolar cycloaddition of nitrones with electron-deficient dipolarophiles

โœ Scribed by Padwa, Albert; Fisera, Lubor; Koehler, Konrad F.; Rodriguez, Augusto; Wong, George S. K.

Book ID
126807454
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
827 KB
Volume
49
Category
Article
ISSN
0022-3263

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Mechanisms of 1.3-dipolar cycloadditions
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โœ Yau-Min Chang; Joyner Sims; K.N. Houk ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

Cycloaddition mechanisms can be separated phenomenologically into three classes. (1) concerted, (2) stepwise--diradical intermediate, and (3) stepwise--zwitterionic intermediate.