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1,3-Dipolar cycloaddition reactions of diazopyrazolinones with electron-deficient dipolarophiles

✍ Scribed by Padwa, Albert; Woolhouse, Anthony D.; Blount, John J.

Book ID
121455254
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
863 KB
Volume
48
Category
Article
ISSN
0022-3263

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Mechanisms of 1.3-dipolar cycloadditions
Mechanisms of 1.3-dipolar cycloadditions to highly electron-deficient dipolarophiles
✍ Yau-Min Chang; Joyner Sims; K.N. Houk πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 199 KB

Cycloaddition mechanisms can be separated phenomenologically into three classes. (1) concerted, (2) stepwise--diradical intermediate, and (3) stepwise--zwitterionic intermediate.