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Regioselectively modified stereoregular polysaccharides. 2. Synthesis of 3-O-methyl-(1 → 6)-α-D-glucopyranan

✍ Scribed by Kobayashi, Kazukiyo; Sumitomo, Hiroshi


Book ID
127270998
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
520 KB
Volume
14
Category
Article
ISSN
0024-9297

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4-O-alpha-D-Mannopyranosyl-(1-->6)-alpha-D-mannopyranan (7) was prepared via ring-opening polymerization of 1,6-anhydro-2,3-di-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-alpha-D- mannopyranosyl)-beta-D-mannopyranose (5) using phosphorus pentafluoride as initiator in dichloromethane at -60 degrees C, follo