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RegioselectiveC-alkylation of alkyl 4-hydroxy-2-methylthiophene-3-carboxylates with α-halo ketones

✍ Scribed by M. M. Krayushkin; V. Z. Shirinian; D. M. Nikalin; A. A. Shimkin

Book ID
111607658
Publisher
Springer
Year
2004
Tongue
English
Weight
273 KB
Volume
53
Category
Article
ISSN
1573-9171

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✍ Petra Štefanič; Katja Turnšek; Danijel Kikelj 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 138 KB

A general synthesis of new alkyl 4-alkyl-2-hydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazine-2-carboxylate peptidomimetic building blocks from the corresponding alkyl 3-oxo-3,4-dihydro-2H-1,4-benzoxazine-2-carboxylates through carbanion oxidation is described.