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Regioselective Synthesis of Nitrofuran Containing Novel Spiropyrrolidine Library through 1,3-Dipolar Cycloaddition Reactions

✍ Scribed by Mallya, Sahana; Kalluraya, Balakrishna; Girisha, K. S.

Book ID
125460237
Publisher
Journal of Heterocyclic Chemistry
Year
2014
Tongue
English
Weight
356 KB
Volume
52
Category
Article
ISSN
0022-152X

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A facile synthesis of novel spiroindane-1,3-diones has been achieved via 1,3-dipolar cycloaddition of an azomethine ylide, generated in situ from ninhydrin and 1,2,3,4-tetrahydroisoquinoline, with the conjugated double bond of chalcone derivatives. The regiochemistry and structures of the cycloadduc

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## Abstract Cycloaddition of an azomethine ylide, generated from ninhydrin and tetrahydroisoquinoline, with chalcones offers a novel diastereoselective synthesis of the target compounds.