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Novel Synthesis of N-Methyl Spiropyrrolidines by 1,3-Dipolar Cycloaddition Reaction of Azomethine Ylides.

โœ Scribed by G. Subramaniyan; J. Jayashankaran; R. Raghunathan

Publisher
John Wiley and Sons
Year
2005
Weight
14 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of spiropyrrolidines: 1,3-dipolar cycloaddition reactions of an azomethine ylide to unusual dipolarophiles; a molecular orbital study of the cycloaddition reaction
โœ A. Amal Raj; R. Raghunathan; E. J. P. Malar ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 312 KB ๐Ÿ‘ 2 views

A simple and efficient method for the synthesis of novel spiropyrrolidines has been accomplished by regioselective 1,3-dipolar cycloaddition reactions of an azomethine ylide generated by thermalring opening of cis-1-cyclohexyl-2-phenyl-3-benzoyl aziridine with various (E)-3-arylidene-4-chromanones.