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Regioselective Synthesis of 3-Hydroxyorthanilic Acid and Its Biotransformation into a Novel Phenoxazinone Dye by Use of Laccase

✍ Scribed by Frédéric Bruyneel; Estelle Enaud; Ludovic Billottet; Sophie Vanhulle; Jacqueline Marchand-Brynaert


Book ID
102178124
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
363 KB
Volume
2008
Category
Article
ISSN
1434-193X

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Synthesis of a novel heterospirocyclic 3
✍ José M. Villalgordo; Heinz Heimgartner 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 586 KB

## The synthesis of a novel heterospirocyclic 3-amino-2H-asirine based on the reaction between amide enolates and diphenylphosphorochloridate is described. This compound has been shown to be a useful amino acid equivalent and the synthesis of a model m@pdde was achieved in good overall yields. 164