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Regioselective Suzuki Cross-Coupling Reactions at the 2-Position of Di- and Tribrominated Pyrroles.

✍ Scribed by Sven Schroeter; Thorsten Bach


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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Functionalisation of the 1-Phosphanorbor
✍ Virginie MouriΓ¨s; FranΓ§ois Mercier; Louis Ricard; FranΓ§ois Mathey πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 214 KB πŸ‘ 1 views

The reaction of alkynylstannanes with 1-phenyl-3,4-1-oxide confirms the functionalisation at the Ξ±-position and the relief of ring strain taking place upon insertion of oxygen dimethylphosphole at 150 Β°C affords the corresponding 2stannyl-1-phosphanorbornadienes (2a,b), in fair yield. into the P-CH