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ChemInform Abstract: Functionalization of the 1-Phosphanorbornadiene Structure at the C2 Position by Stille Cross-Coupling Reactions.

✍ Scribed by V. MOURIES; F. MERCIER; L. RICARD; F. MATHEY

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Functionalisation of the 1-Phosphanorbor
Functionalisation of the 1-Phosphanorbornadiene Structure at the C2 Position by Stille Cross-Coupling Reactions
✍ Virginie MouriΓ¨s; FranΓ§ois Mercier; Louis Ricard; FranΓ§ois Mathey πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 214 KB

The reaction of alkynylstannanes with 1-phenyl-3,4-1-oxide confirms the functionalisation at the Ξ±-position and the relief of ring strain taking place upon insertion of oxygen dimethylphosphole at 150 Β°C affords the corresponding 2stannyl-1-phosphanorbornadienes (2a,b), in fair yield. into the P-CH