✦ LIBER ✦

Regioselective reductive: Elimination of aryloxymethylethynylcarbinols - synthesis of aryloxymethylallenes

✍ Scribed by T Rajamannar; K.K Balasubramanian

Book ID: 104217994
Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 178 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)83878-2

No coin nor oath required. For personal study only.

✦ Synopsis

Exclusive formation of allenes and alkenols during the reduction of aryloxymethylethynylcarbinols and ethynylcarbinols respectively, with lithium aluminiumhydride, is being reported.

📜 SIMILAR VOLUMES

Synthesis and Reductive Elimination Reac

Synthesis and Reductive Elimination Reactions of Aryl Thioglycosides

✍ Fürstner, Alois 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 772 KB

## Abstract Treatment of the sugar hemiacetals 1, 5, 7, 10, 12 and 14 with ArSSAr (Ar = phenyl, 2‐pyridyl, 2‐benzothiazolyl) and trialkylphosphanes affords in an S~N~2 process the corresponding aryl thioglycosides 3, 6, 8, 9, 11, 13, 15 and 16 in good to excellent yields. The reaction can be perfor

Synthesis of alkenes by reductive elimin

Synthesis of alkenes by reductive elimination of .beta.-hydroxysulfoximines

✍ Johnson, Carl R.; Kirchhoff, Robert A. 📂 Article 📅 1979 🏛 American Chemical Society 🌐 English ⚖ 821 KB

Synthesis, Isolation, and Characterizati

Synthesis, Isolation, and Characterization of an Organometallic Triiodopalladium(IV) Complex. Quantitative and Regioselective Synthesis of Two C–I Reductive Elimination Products

✍ Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia 📂 Article 📅 2011 🏛 American Chemical Society 🌐 English ⚖ 758 KB

Mechanism and Regioselectivity of Reduct

Mechanism and Regioselectivity of Reductive Elimination of π-Allylcopper (III) Intermediates

✍ Yamanaka, Masahiro; Kato, Seiichi; Nakamura, Eiichi 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 330 KB

Olefin synthesis by reductive eliminatio

Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides

✍ K. Sevrin; J.N. Denis; A. Krief 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 248 KB

Synthesis and reductive elimination of t

Synthesis and reductive elimination of triarylbis(phenylethynyl)antimony (v)

✍ Kin-ya Akiba; Takaaki Okinaka; Masayuki Nakatani; Yohsuke Yamamoto 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 143 KB