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Synthesis and reductive elimination of triarylbis(phenylethynyl)antimony (v)

✍ Scribed by Kin-ya Akiba; Takaaki Okinaka; Masayuki Nakatani; Yohsuke Yamamoto

Book ID
108382772
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
143 KB
Volume
28
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Synthesis and Reductive Elimination Reac
Synthesis and Reductive Elimination Reactions of Aryl Thioglycosides
✍ FΓΌrstner, Alois πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 772 KB

## Abstract Treatment of the sugar hemiacetals 1, 5, 7, 10, 12 and 14 with ArSSAr (Ar = phenyl, 2‐pyridyl, 2‐benzothiazolyl) and trialkylphosphanes affords in an S~N~2 process the corresponding aryl thioglycosides 3, 6, 8, 9, 11, 13, 15 and 16 in good to excellent yields. The reaction can be perfor