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Regioselective reductive alkylation of 1,2,3-trimethoxybenzene

✍ Scribed by Ugo Azzena; Sergio Cossu; Teresa Denurra; Giovanni Melloni; Anna Maria Piroddi

Book ID
104229707
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
177 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

The a-tnethoxyl group of 1,2,+trimethoxybenzene and its 5-methyl-substituted hcnnologue is removed under reductive electron transfer conditions and replaced with an alkyl group in a one-pot procedure.

πŸ“œ SIMILAR VOLUMES

Acid-mediated regioselective alkylation
Acid-mediated regioselective alkylation of 1,2,3-triazole
✍ Andrei O. Korenm πŸ“‚ Article πŸ“… 2002 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 22 KB

## Abstract 1,2,3‐Triazole reacts with isopropyl alcohol in concentrated sulfuric acid to yield 1‐isopropyl‐1__H__‐1,2,3‐triazole as the only reaction product.