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Regioselective photoaddition of alcohols to 1,2,3-butatriene derivatives via photoinduced electron transfer

โœ Scribed by Hajime Maeda; Shogo Nishioka; Kazuhiko Mizuno


Book ID
104254255
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
97 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Photochemical polar addition of alcohols to 1,1-diaryl-1,2,3-butatriene derivatives in the presence of a catalytic amount of 9,10-dicyanoanthracene regioselectively afforded 1,1-diaryl-4-alkoxy-1,2-butadienes as addition products in good yields via photoinduced electron transfer.


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ฮฑ-Regioselective and stereospecific addi
โœ Akio Takuwa; Junji Shiigi; Yutaka Nishigaichi ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 241 KB

## Allylic tributyltins add to aromatic alakhydes to afford regioreversed a-a&iuct predominantly with almost complete retention of the stereochemistry of the allylic groups under photochemical conditions. The photoinduced single ekctron transfer mechanism is proposed. The addition of allyltin reag