Regioselective photoaddition of alcohols to 1,2,3-butatriene derivatives via photoinduced electron transfer
โ Scribed by Hajime Maeda; Shogo Nishioka; Kazuhiko Mizuno
- Book ID
- 104254255
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 97 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Photochemical polar addition of alcohols to 1,1-diaryl-1,2,3-butatriene derivatives in the presence of a catalytic amount of 9,10-dicyanoanthracene regioselectively afforded 1,1-diaryl-4-alkoxy-1,2-butadienes as addition products in good yields via photoinduced electron transfer.
๐ SIMILAR VOLUMES
## Allylic tributyltins add to aromatic alakhydes to afford regioreversed a-a&iuct predominantly with almost complete retention of the stereochemistry of the allylic groups under photochemical conditions. The photoinduced single ekctron transfer mechanism is proposed. The addition of allyltin reag