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Regioselective Photoaddition of Alcohols to 1,2,3-Butatriene Derivatives via Photoinduced Electron Transfer.

โœ Scribed by Majime Maeda; Shogo Nishioka; Kazuhiko Mizuno


Book ID
101954541
Publisher
John Wiley and Sons
Year
2003
Weight
92 KB
Volume
34
Category
Article
ISSN
0931-7597

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Regioselective photoaddition of alcohols
โœ Hajime Maeda; Shogo Nishioka; Kazuhiko Mizuno ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 97 KB

Photochemical polar addition of alcohols to 1,1-diaryl-1,2,3-butatriene derivatives in the presence of a catalytic amount of 9,10-dicyanoanthracene regioselectively afforded 1,1-diaryl-4-alkoxy-1,2-butadienes as addition products in good yields via photoinduced electron transfer.

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## Allylic tributyltins add to aromatic alakhydes to afford regioreversed a-a&iuct predominantly with almost complete retention of the stereochemistry of the allylic groups under photochemical conditions. The photoinduced single ekctron transfer mechanism is proposed. The addition of allyltin reag