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Regioselective oxidation of the methyl ester of maleopimaric acid by dimethyldioxirane

✍ Scribed by Nazyrov, T. I.; Tret’yakova, E. V.; Kazakova, O. B.; Spirikhin, L. V.; Kukovinets, O. S.

Book ID
120510585
Publisher
Springer
Year
2013
Tongue
English
Weight
57 KB
Volume
48
Category
Article
ISSN
0009-3130

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Selective dimethyldioxirane oxidation of
Selective dimethyldioxirane oxidation of bile acid methyl esters
✍ P.Christopher Buxton; Brian A. Marples; Richard C. Toon; Victoria L. Waddington 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 247 KB

DMDO oxidation of the hydroxy groups of bile acid methyl esters establishes the positional order of reactivity as 3-7 > 6 > 12 and supports a mechanism involving C-H oxygen insertion through a planar intramolecularly hydrogen bonded transition state.