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Regioselective Nitration of Phenols by NaNO 3 in Microemulsion

✍ Scribed by Jiang, Jian-Zhong; Lu, Li-Ting; Liang, Zheng-Yong; Cui, Zheng-Gang; Qi, Li-Yun

Book ID
120666734
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
138 KB
Volume
32
Category
Article
ISSN
0193-2691

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✍ T. Esakkidurai; K. Pitchumani πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 59 KB

Phenol (I) is nitrated regioselectively by fuming nitric acid inside the cages of faujasite zeolites. While nitration as hexane slurry in CsY and molecular sieve 5 Γ… leads to predominant formation of para-nitrophenol (III), a remarkable ortho-selectivity is observed in solid state nitration to yield