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Regioselective Nitration of Phenol Induced by Catalytic Antibodies

✍ Scribed by Rémy Ricoux; Elodie Girgenti; Hélène Sauriat-Dorizon; Dominique Blanchard; Jean-Pierre Mahy

Book ID
110407595
Publisher
Springer
Year
2002
Tongue
English
Weight
43 KB
Volume
21
Category
Article
ISSN
1573-4943

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Zeolite-mediated regioselective nitratio
Zeolite-mediated regioselective nitration of phenol in solid state
✍ T. Esakkidurai; K. Pitchumani 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 59 KB

Phenol (I) is nitrated regioselectively by fuming nitric acid inside the cages of faujasite zeolites. While nitration as hexane slurry in CsY and molecular sieve 5 Å leads to predominant formation of para-nitrophenol (III), a remarkable ortho-selectivity is observed in solid state nitration to yield