Regioselective epoxidation of geraniol with m-chloroperbenzoic acid in emulsion systems
β Scribed by Masaki Nakamura; Nobuyasu Tsutsui; Tokuji Takeda; Takashi Tokoroyama
- Book ID
- 104242209
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 119 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The selectivity of the three different double bonds (CIS, TRANS and VINYL) of hydroxyterminated polybutadiene regarding epoxidation was evaluated, using __m__βchloroperbenzoic acid in toluene below room temperature (β10Β°C, β5Β°C, 0Β°C and 5Β°C). To determine the kinetic constants for the t
The expoxidation of ethyl linolenate (ethyl (Z)-9-(Z)-12-(Z)-15-octadecatrienoate) (i) with m-chloroperbenzoic acid is described. When the reaction was performed using one mole of peracid per mole of (i), the three monoepoxides of (i), namely, ethyl c/s-9,10-epoxy-(Z)-12-(Z)-15-octadecadienoate (if)