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Stereoselective Epoxidation of Allylic Carbamates with m-Chloroperbenzoic Acid: The Role of Cooperative Coordination

✍ Scribed by Jenmalm, Annika; Berts, Wei; Luthman, Kristina; Csoeregh, Ingeborg; Hacksell, Uli


Book ID
126290208
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
829 KB
Volume
60
Category
Article
ISSN
0022-3263

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Configurational double bond selectivity
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## Abstract The selectivity of the three different double bonds (CIS, TRANS and VINYL) of hydroxyterminated polybutadiene regarding epoxidation was evaluated, using __m__‐chloroperbenzoic acid in toluene below room temperature (βˆ’10Β°C, βˆ’5Β°C, 0Β°C and 5Β°C). To determine the kinetic constants for the t