𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Regioselective Electrophilic Trifluoromethylation of Indolines, Oxindolines and Indoles in Superacid.

✍ Scribed by Sebastien Debarge; Kenza Kassou; Helene Carreyre; Bruno Violeau; Marie-Paule Jouannetaud; Jean-Claude Jacquesy

Book ID
111699555
Publisher
John Wiley and Sons
Year
2004
Weight
117 KB
Volume
35
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Regioselective electrophilic trifluorome
Regioselective electrophilic trifluoromethylation of substituted anilines and derivatives in superacid
✍ SΓ©bastien Debarge; Bruno Violeau; Nohair Bendaoud; Marie-Paule Jouannetaud; Jean πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 223 KB

In a one pot procedure, treatment of chloro or methyl substituted acetanilides in HF/SbF 5 /CCl 4 followed by addition of HF/pyridine yields trifluoromethyl derivatives with high regioselectivity.

Hydroxylation of indolines and indoles b
Hydroxylation of indolines and indoles by hydrogen peroxide in superacids
✍ Christian Berrier; Jean-Claude Jacquesy; Marie-Paule Jouannetaud; Alain Renoux πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 165 KB

In SbFS-HF, indolines and indoles are hydroxylated on the aromatic ring, protonated hydrogen peroxide H302+ reacting on the protonated substrates. Electrophilic hydroxylation of aromatics has been intensively studied and it has been shown that hydrogen peroxide in superacidic media is a convenient r