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Regioselective catalytic transfer hydrogenation of dimethyl bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate, dimethyl bicyclo[2.2.1]hept-2-ene-2,3-dicarboxylate, and related compounds over palladium on carbon

โœ Scribed by Tabor, Derrick C.; White, Franklin; Collier, L. Warren; Evans, Slayton A.


Book ID
118186699
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
781 KB
Volume
48
Category
Article
ISSN
0022-3263

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Swrmary: A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicycloE.2.gheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides. Recent papers on the synthesis of prostaglandin endoperoxide ana