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One-pot palladium-catalyzed synthesis of 2,3-disubstituted bicyclo[2.2.1]heptanes and bicyclo[2.2.1]hept-5-enes

✍ Scribed by Marta Catellani; Gian Paolo Chiusoli

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 186 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85642-7

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✦ Synopsis

Swrmary: A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicycloE.2.gheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides.

Recent papers on the synthesis of prostaglandin endoperoxide analogs' prompt us to report a new catalytic synthesis resulting from our studies on palladium-catalyzed insertion processes.2-4

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