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Regioselective Bond Cleavage in the Dissociative Electron Transfer to Benzyl Thiocyanates

โœ Scribed by Houmam, Abdelaziz; Hamed, Emad M.; Hapiot, Philippe; Motto, John M.; Schwan, Adrian L.


Book ID
125928970
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
64 KB
Volume
125
Category
Article
ISSN
0002-7863

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Single electron transfer reductive cleav
โœ U. Azzena; F. Dessanti; G. Melloni; L. Pisano ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

By treatment with Li metal in THF at room temperature the three isomeric N,N-dimethylaminobiphenyls and NJ-dimethyl-2,6-diphenylanilineunderwent 100% regioselective reductive cleavage of the aryl-N bond, affording biphenyl and me&-terphenyl, respectively, in various yields.