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Single electron transfer reductive cleavage of the aryl-nitrogen bond in phenyl-substituted dimethylanilines

✍ Scribed by U. Azzena; F. Dessanti; G. Melloni; L. Pisano

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 216 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01758-x

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✦ Synopsis

By treatment with Li metal in THF at room temperature the three isomeric N,N-dimethylaminobiphenyls and NJ-dimethyl-2,6-diphenylanilineunderwent 100% regioselective reductive cleavage of the aryl-N bond, affording biphenyl and me&-terphenyl, respectively, in various yields.

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