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Regioselective and stereospecific palladium(0)-catalyzed reactions of 4-chloroacetoxyalk-2-enoic esters with carbon and nitrogen nucleophiles

โœ Scribed by Tanikaga, Rikuhei; Jun, Tuo Xiao; Kaji, Aritsune


Book ID
119940853
Publisher
Royal Society of Chemistry
Year
1990
Weight
897 KB
Volume
4
Category
Article
ISSN
1472-7781

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Palladium-catalyzed regioselective react
โœ Jiro Tsuji; Hiroaki Ueno; Yuichi Kobayashi; Hiroshi Okumoto ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 120 KB

e-Acetoxy-8,y-unsaturated nitriles react at room temperature with malonates and acetoacetates in the presence of palladium-phosphine complexes as a catalyst to give y-substituted a,8-unsaturated nitriles selectively. Also yacetoxy-a,8-unsaturated ester was attacked at y-position by malonate.