A highly regioselective reduction of propargylic acetates has been attained by using SmI2 and catalytic Pd(O) in the presence of 2,4-dimethyl-3-pentanol affording various types of allenes in high yields. Allenes not only constitute an important class of natural products but also serve as useful inte
โฆ LIBER โฆ
Palladium(0)-catalyzed reaction of propargylic phosphates with SmI2: A highly regioselective route to the synthesis of allenes and acetylenes
โ Scribed by Koichi Mikami; Akihiro Yoshida; Shoji Matsumoto; Feng Feng; Youichi Matsumoto; Akihiro Sugino; Takeshi Hanamoto; Junji Inanaga
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 87 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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