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Regioselective and stereoselective reductive cleavage of 1,7-dioxaspiro[5.5]undecane alcohols

✍ Scribed by Michael T Crimmins; Stephen W Rafferty

Book ID: 103411820
Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 224 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(96)01196-3

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## Abstract Quick access to polyfunctional spiroketal (3__R__)‐4[(2__S__,6__R__,8__R__,10__S__)‐4,4‐bis(ethylthio)‐10‐hydroxy‐8‐(2‐hydroxyethyl)‐1,7‐dioxaspiro[5.5]undec‐2‐yl]butane‐1,3‐diol [(+)‐**19**] is now available through the stereoselective functionalization of enantiomerically pure protect