Regioselective and stereoselective PPh3 substitution in the imido-capped cluster Ru3(CO)10(μ3-NPh). Electrochemical properties and X-ray diffraction structures of Ru3(CO)9(PPh3)(μ3-NPh) and Ru3(CO)8(PPh3)2(μ3-NPh)·12CH2Cl2
✍ Scribed by Huafeng Shen; Robert A. Senter; Simon G. Bott; Michael G. Richmond
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 875 KB
- Volume
- 247
- Category
- Article
- ISSN
- 0020-1693
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The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d
## Dedicated to Prof. Huns-Georg uon Schnering on the occasion of his 60th birthday (1 7.V. 9 I) The cluster compounds [Pt,(,u-CO),(PR,),] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX,, and Group XIII, MX,, to form cluster compounds of the composition [{MX,}{Pt3(,u-