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Regiochemistry of the rearrangement of cyclohexenyl and cyclohexadienyl phosphates to .beta.-keto phosphonates

✍ Scribed by Gloer, Katherine B.; Calogeropoulou, Theodora; Jackson, John A.; Wiemer, David F.


Book ID
126311501
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
717 KB
Volume
55
Category
Article
ISSN
0022-3263

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1,3-Phosphorotropic rearrangement of pyr
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## Abstract The lithium diisopropylamide (LDA) induced regioselective 1,3‐rearrangement of 3‐ and 2‐ pyridyl phosphates into the corresponding 3‐hydroxy‐4‐pyridyl‐and 2‐hydroxy‐3‐pyridylphosphonates has been observed and investigated. The rearrangement is proposed as a useful method for a directed