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Regiochemical control in the homo-Diels-Alder reaction: substituent effects

โœ Scribed by Lautens, Mark; Edwards, Louise G.


Book ID
126919874
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
406 KB
Volume
56
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Stereoselectivity in the Homo Diels-Alde
โœ Mark Lautens; Louise G. Edwards ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

Ni(COD)z/Ph3P or Ni(acac)2/Et3Al/PhsP have been shown to be effective catalysts for the stereoselective homo Diels-Alder reaction between norbomadiene and electron deficient olefins. High and opposite stereoselectivity was observed for cyclic and acyclic enones. Vinyl sulfoxides gave predominantly o