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Catalytic asymmetric induction in the homo Diels-Alder reaction

โœ Scribed by Lautens, Mark; Lautens, Julia Craig; Smith, A. Catherine

Book ID
120804105
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
325 KB
Volume
112
Category
Article
ISSN
0002-7863

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Asymmetric inductive effects have been measured on the Diels-Alder reaction of dimethyl fumarate with o-quinodimethane bearing a chiral u-alkoxy group. The chiral substituents used were f-phenylethoxy, 2-(1-phenyl)propoxy, 1-(2\_phenyl)propoxy, 2-(4-phenyljbutoxy and l-cyclohexylethoxy. The greatest