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Regio- and stereospecific hydrophosphorylation of phenylacetylene

✍ Scribed by Arcady I. Kuramshin; Andrey A. Nikolaev; Rafael A. Cherkasov


Book ID
111730592
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
196 KB
Volume
15
Category
Article
ISSN
0959-9436

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Regio- and stereospecific addition of ph
✍ Nina K Gusarova; Svetlana I Shaikhudinova; Svetlana N Arbuzova; Tamara I Vakul's πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 147 KB

Primary and secondary phosphines add regio-and stereospecifically to phenylcyanoacetylene and 4-hydroxy-4-methylpent-2ynenitrile under mild conditions to form corresponding functionalized secondary and tertiary phosphines of Z-configuration in 70 -91% yield. According to ESR and UV data, the additio