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Regio- and stereospecific addition of phosphines to cyanoacetylenes

โœ Scribed by Nina K Gusarova; Svetlana I Shaikhudinova; Svetlana N Arbuzova; Tamara I Vakul'skaya; Boris G Sukhov; Lidiya M Sinegovskaya; Mikhail V Nikitin; Anastasiya G Mal'kina; Nataliya A Chernysheva; Boris A Trofimov

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
147 KB
Volume
59
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

โœฆ Synopsis

Primary and secondary phosphines add regio-and stereospecifically to phenylcyanoacetylene and 4-hydroxy-4-methylpent-2ynenitrile under mild conditions to form corresponding functionalized secondary and tertiary phosphines of Z-configuration in 70 -91% yield. According to ESR and UV data, the addition of primary phosphines to phenylcyanoacetylene involves a single electron transfer process.

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