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Enantioselective Addition of Secondary Phosphines to Methacrylonitrile: Catalysis and Mechanism.

✍ Scribed by Aaron D. Sadow; Antonio Togni


Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract Secondary phosphine sulfide and selenide (II) are regiospecifically added to alkyl vinyl telluride (I) under radical initiation furnishing anti‐Markovnikov‐adducts (III) (4 examples) in good yields.